| Autor: |
Lev N. Sidorov, Sergey I. Troyanov, Ilya N. Ioffe, Erhard Kemnitz, Alexey A. Goryunkov, Marina G. Apenova, Pavel A. Khavrel, N. S. Ovchinnikova, Marina A. Yurovskaya, Nikita M. Belov |
| Rok vydání: |
2010 |
| Předmět: |
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| Zdroj: |
Dalton transactions (Cambridge, England : 2003). 40(4) |
| ISSN: |
1477-9234 |
| Popis: |
The Bingel reaction of the C(s) isomer of C(70)(CF(3))(8) has been found to yield two C(70)(CF(3))(8)[C(CO(2)Et)(2)] monoadducts and one C(70)(CF(3))(8)[C(CO(2)Et)(2)](2) bisadduct as its major products. Malonate addition occurs at those [6,6]-bonds that radiate from the polar pentagons of the C(70)(CF(3))(8) cage. Unexpectedly, X-ray single crystal analysis reveals dimerization of the above substances during crystallization, providing two isomers of {C(70)(CF(3))(8)[C(CO(2)Et)(2)]}(2), one isomer of {C(70)(CF(3))(8)[C(CO(2)Et)(2)](2)}(2) and {C(70)(CF(3))(8)}(2). This dimerization represents [2+2]-cycloaddition via [5,6]-bonds and results in functionalization patterns resembling several known C(70)X(10) derivatives. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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