Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour
| Autor: | Madeline Basile, Mikaela M. Pyrch, Maurice K. Payne, Matthew Jubinsky, Tori Z. Forbes |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Nanotube
Metals and Alloys 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Uranyl 01 natural sciences Catalysis Thermal expansion 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal chemistry.chemical_compound chemistry Chemical engineering visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium 0210 nano-technology |
| Zdroj: | Chemical Communications. 54:10828-10831 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c8cc05240a |
| Popis: | Physical properties of actinyl materials are influenced by the presence of oxo functional groups. Herein, we report large thermal expansion coefficients for a uranyl metal organic nanotube that switch from positive to negative upon dehydration. Different behaviour is observed in the neptunyl system due to variations in the oxo interactions. |
| Databáze: | OpenAIRE |
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