Barium Azacryptand Sodide, the First Alkalide with an Alkaline Earth Cation, Also Contains a Novel Dimer, (Na2)2

Autor:	James E. Jackson, Mikhail Y. Redko, James L. Dye, Rui H. Huang, James F. Harrison
Rok vydání:	2003
Předmět:	Alkaline earth metal Stereochemistry Alkalide Dimer chemistry.chemical_element Barium General Chemistry Crystal structure Biochemistry Magnetic susceptibility Catalysis chemistry.chemical_compound Crystallography Colloid and Surface Chemistry chemistry Spectroscopy Stoichiometry
Zdroj:	Journal of the American Chemical Society. 125:2259-2263
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja027241m
Popis:	The first barium sodide, with stoichiometry Ba(2+)(H(5)Azacryptand[2.2.2](-))Na(-).2MeNH(2), was synthesized by the reaction of Ba, Na, and H(6)Azacryptand[2.2.2] in NH(3)-MeNH(2) solution. It was characterized by X-ray crystallography, (23)Na MAS NMR, hydrogen evolution, DSC, optical spectroscopy, and magnetic susceptibility. This is the first sodide in which the sodium anions form (Na(2))(2)(-) dimers. Previous theoretical predictions were verified by a calculation of the potential energy curve for the dimer in the field of the surrounding charges, whose positions were determined from the crystal structure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7fee175d668085c0f412559b048e2dc2 https://doi.org/10.1021/ja027241m Zobrazit plný text záznamu