Microwave assisted synthesis of polynuclear Ni(II) complexes
| Autor: | Lidia Rosado Piquer, E. Carolina Sañudo |
|---|---|
| Přispěvatelé: | Universitat de Barcelona |
| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Chemistry Ligand Propietats magnètiques 010402 general chemistry 01 natural sciences Microwave assisted Complexos metàl·lics 0104 chemical sciences Inorganic Chemistry Metal complexes Polymer chemistry Magnetic properties Materials Chemistry Physical and Theoretical Chemistry |
| Zdroj: | Dipòsit Digital de la UB Universidad de Barcelona Recercat. Dipósit de la Recerca de Catalunya instname |
| Popis: | In this paper we test a solvent-free microwave assisted synthesis method with a known Ni7 complex, [Ni7(chp)12(OH)2(CH3OH)6] (2), and then extended the method to a more complex ligand system. We prepare two new trinuclear Ni(II) complexes ([Ni3(chp)4(tBuSALOH)2(MeOH)5] (4) and [Ni3(chp)4(iPrSALOH)2(MeOH)6] (5)) and report here their characterization and magnetic properties. |
| Databáze: | OpenAIRE |
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