Thermodynamic and thermophysical properties of Cu-Si liquid alloys
| Autor: | Luca Soldi, Jürgen Brillo, Mathieu Roskosz, Andrea Quaini, Stéphane Gossé |
|---|---|
| Přispěvatelé: | Laboratoire de Modélisation, Thermodynamique et Thermochimie (LM2T), Service de la Corrosion et du Comportement des Matériaux dans leur Environnement (SCCME), Département de Physico-Chimie (DPC), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Département de Physico-Chimie (DPC), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, Deutsches Zentrum für Luft- und Raumfahrt [Köln] (DLR), Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
[PHYS]Physics [physics]
Materials science 020502 materials Drop (liquid) Industrial scale 0211 other engineering and technologies Intermetallic Thermodynamics 02 engineering and technology Condensed Matter Physics 7. Clean energy Surface tension [SPI]Engineering Sciences [physics] 0205 materials engineering Mechanics of Materials Scientific method surface tension thermodynamics Cu-Si [CHIM]Chemical Sciences Physical and Theoretical Chemistry CALPHAD Magnetic levitation ComputingMilieux_MISCELLANEOUS 021102 mining & metallurgy Eutectic system |
| Zdroj: | High Temperatures-High Pressures High Temperatures-High Pressures, Old City Publishing, 2020, 49 (1-2), pp.155-171. ⟨10.32908/hthp.v49.845⟩ High Temperatures-High Pressures, 2020, 49 (1-2), pp.155-171. ⟨10.32908/hthp.v49.845⟩ |
| ISSN: | 0018-1544 1472-3441 |
| DOI: | 10.32908/hthp.v49.845⟩ |
| Popis: | The Cu-Si system is of primary interest for many industrial applications, especially for waste applications. Due to eutectic reactions and the con- gruent melting of intermetallic phases, these binary alloys exhibit specific behaviors as a function of temperature and composition. A complete investigation of the thermodynamic and thermophysical properties of such liquid metals that may form is required to optimize such a process at the industrial scale. To better predict the thermophysical properties of these metallic alloys, measurements of the surface tension are carried out for bulk mole frac- tions of up to 32% at Si. These experiments were conducted by means of the oscillating drop technique using the electromagnetic levitation method [1]. To better predict the thermodynamics of such liquids during the experiments, these tests were complemented by chemical activity cal- culations using the Calphad method. The experimental results obtained from the electromagnetic technique are compared and discussed taking into consideration the Egry model [2], the most suitable one in case of formation of high-temperature intermetal- lic compounds. |
| Databáze: | OpenAIRE |
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