Dry mechanochemical synthesis of hydroxyapatites from DCPD and CaO: influence of instrumental parameters on the reaction kinetics
| Autor: | Philippe Boudeville, Josep A. Planell, Hassane El Briak-BenAbdeslam, Maria-Pau Ginebra, A. Terol, Carolina Mochales |
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| Rok vydání: | 2004 |
| Předmět: |
Calcium Phosphates
Materials science Friction Biophysics Thermodynamics Mineralogy Biocompatible Materials Bioengineering Kinetic energy Biomaterials Chemical kinetics Motion chemistry.chemical_compound Reaction rate constant Mechanochemistry Materials Testing Computer Simulation Calcium oxide Ball mill Oxides Calcium Compounds Grinding Kinetics Models Chemical chemistry Mechanics of Materials Chemical Industry Bone Substitutes Ceramics and Composites Hydroxyapatites Mechanosynthesis |
| Zdroj: | Biomaterials. 25:1151-1158 |
| ISSN: | 0142-9612 |
| Popis: | Mechanochemistry is a possible route to synthesize calcium deficient hydroxyapatite (CDHA) with an expected molar calcium-to-phosphate (Ca/P) ratio ±0.01. To optimize the experimental conditions of CDHA preparation from dicalcium phosphate dihydrate (DCPD) and calcium oxide by dry mechanosynthesis reaction, we performed the kinetic study varying some experimental parameters. This kinetic study was carried out with two different planetary ball mills (Retsch or Fritsch Instuments). Results obtained with the two mills led to the same conclusions although the values of the rate constants of DCPD disappearance and times for complete reaction were very different. Certainly, the origin of these differences was from the mills used, thus we investigated the influence of instrumental parameters such as the mass and the surface area of the balls or the rotation velocity on the mechanochemical reaction kinetics of DCPD with CaO. Results show that the DCPD reaction rate constant and the inverse of the time for complete disappearance of CaO both vary linearly with (i) the square of the rotation velocity, (ii) the square of eccentricity of the vial on the rotating disc and (iii) the product of the mass by the surface area of the balls. These observations comply with theoretical models developed for mechanical alloying. The consideration of these four parameters allows the transposition of experimental conditions from one mill to another or the comparison between results obtained with different planetary ball mills. These instrumental parameters have to be well described in papers concerning mechanochemistry or when grinding is an important stage in a process. |
| Databáze: | OpenAIRE |
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