Divergent cyanoalkylation/cyanoalkylsulfonylation of enamides under organophotoredox catalytic conditions

Autor:	Durga Golagani, Abuthayir Mohamathu Ghouse, Sriram Ajmeera, Srirama Murthy Akondi
Rok vydání:	2022
Předmět:	Molecular Structure Organic Chemistry Esters Physical and Theoretical Chemistry Amides Biochemistry Catalysis
Zdroj:	Organic & Biomolecular Chemistry. 20:8599-8604
ISSN:	1477-0539 1477-0520
Popis:	An organophotoredox-catalyzed divergent cyanoalkylation/cyanoalkylsulfonylation of enamides in a highly regio- and stereoselective manner has been reported. In this mild and efficient protocol, cyclobutanone oxime esters serve as a cyanoalkylating source and inexpensive Ksub2/subSsub2/subOsub5/subserves as an SOsub2/subsurrogate. Broad substrate scope, compatibility of various sensitive functional groups and further functional group transformation are the highlights of this method.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::72f4394a6765935c58c02f2d2ee77fbd https://doi.org/10.1039/d2ob01775j Zobrazit plný text záznamu