The spectroscopy of molecular reaction intermediates trapped in the solid rare gases

Autor:	Marilyn E. Jacox
Rok vydání:	2002
Předmět:	Neon Argon chemistry Computational chemistry Ab initio quantum chemistry methods Ab initio Infrared spectroscopy chemistry.chemical_element General Chemistry Reaction intermediate Photochemistry Spectroscopy Electron spectroscopy
Zdroj:	Chemical Society Reviews. 31:108-115
ISSN:	1460-4744 0306-0012
DOI:	10.1039/b102907j
Popis:	The trapping of neutral and electrically charged molecular reaction intermediates in the solid rare gases and the characterization of these intermediates by vibrational and electronic spectroscopy are surveyed. Spectral data for reaction intermediates trapped in solid neon and argon are compared with the corresponding data obtained from gas phase studies and from quantum chemical calculations. Emphasis is placed on recent progress, including the production, stabilization, and spectroscopic study of highly reactive small molecular ions and the use of ab initio and density functional calculations for the identification of reaction intermediates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::72ab05b7daf2b2ddef2fb9346335573c https://doi.org/10.1039/b102907j Zobrazit plný text záznamu