Thermal Stability and Reactivity of Cathode Materials for Li-Ion Batteries
| Autor: | Fredrick Omenya, Natasha A. Chernova, M. Stanley Whittingham, David M. Jenkins, Shyue Ping Ong, Yiqing Huang, Youngmin Chung, Jin Fang, Iek-Heng Chu, Yuh-Chieh Lin, Balachandran Radhakrishnan, Qi Wang |
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| Rok vydání: | 2016 |
| Předmět: |
Thermogravimetric analysis
Materials science 020209 energy Analytical chemistry Nanotechnology 02 engineering and technology Electrolyte 021001 nanoscience & nanotechnology Cathode law.invention Differential scanning calorimetry law Phase (matter) 0202 electrical engineering electronic engineering information engineering General Materials Science Thermal stability Reactivity (chemistry) 0210 nano-technology Phase diagram |
| Zdroj: | ACS Applied Materials & Interfaces. 8:7013-7021 |
| ISSN: | 1944-8252 1944-8244 |
| DOI: | 10.1021/acsami.5b12081 |
| Popis: | The thermal stability of electrochemically delithiated Li0.1Ni0.8Co0.15Al0.05O2 (NCA), FePO4 (FP), Mn0.8Fe0.2PO4 (MFP), hydrothermally synthesized VOPO4, LiVOPO4, and electrochemically lithiated Li2VOPO4 is investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis, coupled with mass spectrometry (TGA-MS). The thermal stability of the delithiated materials is found to be in the order of NCA < VOPO4 < MFP < FP. Unlike the layered oxides and MFP, VOPO4 does not evolve O2 on heating. Thus, VOPO4 is less likely to cause a thermal run-away phenomenon in batteries at elevated temperature and so is inherently safer. The lithiated materials LiVOPO4, Li2VOPO4, and LiNi0.8Co0.15Al0.05O2 are found to be stable in the presence of electrolyte, but sealed-capsule high-pressure experiments show a phase transformation of VOPO4 → HVOPO4 → H2VOPO4 when VOPO4 reacts with electrolyte (1 M LiPF6 in EC/DMC = 1:1) between 200 and 300 °C. Using first-principles calculations, we confirm that the charged VOPO4 cathode is indeed predicted to be marginally less stable than FP but significantly more stable than NCA in the absence of electrolyte. An analysis of the reaction equilibria between VOPO4 and EC using a multicomponent phase diagram approach yields products and reaction enthalpies that are highly consistent with the experiment results. |
| Databáze: | OpenAIRE |
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