Electrospray mass spectrometry: a study on some aqueous solutions of metal salts

Autor:	Shier S. Berman, Z. L. Cheng, K. W. M. Siu, Roger Guevremont
Rok vydání:	1992
Předmět:	chemistry.chemical_classification Electrospray Aqueous solution Chemistry Electrospray mass spectrometry Analytical chemistry Ionic bonding Salt (chemistry) Ion Metal Structural Biology visual_art Mass spectrum visual_art.visual_art_medium Spectroscopy
Zdroj:	Chemistry and Biochemistry Publications
ISSN:	1044-0305
DOI:	10.1016/1044-0305(92)87055-4
Popis:	Aqueous metal salt solutions were used as models to probe the origin of the species observed in the electrospray mass spectrum. A qualitative or semiquantitative correlation among different species was observed between electrospray responses and calculated equilibrium aqueous solution concentrations. Quantitative correlations were obtained, however, when ions that were identical in charge and similar in type were selected for comparison. In these experiments the ions experienced very similar electrospray-related processes and their effects on the responses were canceled in a comparison of these ions. Consequently, the relative abundances of these ions in the electrospray mass spectrum closely matched the calculated relative abundances in aqueous solution. Our results suggest that the basic principle that determines ionic distribution in the electro spray mass spectrum in aqueous solution chemistry. © 1992 American Society for Mass Spectrometry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::71f1f8c0152dd3a65fdff9db4d2954c8 https://doi.org/10.1016/1044-0305(92)87055-4 Zobrazit plný text záznamu Full text from SpringerLink