A Mesogenic Triphenylene−Perylene−Triphenylene Triad

Autor:	Linping Mu, Xiping Jing, Xiangfei Kong, Yinning Zhang, Zhiqun He, Bo Chen, Chunjun Liang, Andrew N. Cammidge
Rok vydání:	2011
Předmět:	Chemistry Mesogen Organic Chemistry Doping Mesophase Triphenylene Triad (anatomy) Photochemistry Biochemistry chemistry.chemical_compound Crystallography medicine.anatomical_structure medicine Side chain Amine gas treating Physical and Theoretical Chemistry Perylene
Zdroj:	Organic Letters. 13:764-767
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol103018v
Popis:	A straightforward synthesis of triphenylene-perylene-triphenylene triad structures has been achieved by using versatile triphenylene intermediates bearing a single oxyalkyl amine side chain. Among these, PBITP(10) showed a stable columnar mesophase implying favorably matched core-core separations in the structure. Importantly, the triad can be used as a vehicle for doping columnar triphenylene matrices with functional but incompatible perylene units and a mixture of hexahexyloxytriphenylene matrix doped with 0.1% PBITP(10) is homogeneous and liquid crystalline.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6fe278e20f6bbd0fde10fc6d6a2ac206 https://doi.org/10.1021/ol103018v Zobrazit plný text záznamu