Influence of Anti-Caking Agents on the Highly Effective Organic Coatings for Preventing the Caking of Ammonium Nitrate Fertilizers
| Autor: | Józef Hoffmann, Krystyna Hoffmann, Ryszard Grzesik, Aleksandra Tyc, Dominik Nieweś, Szymon Penkala |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
fertilizers Ammonium nitrate 02 engineering and technology organic coatings 010402 general chemistry 01 natural sciences Calcium ammonium nitrate Viscosity chemistry.chemical_compound Materials Chemistry GC–MS anti-caking agents Water content Wax Surfaces and Interfaces 021001 nanoscience & nanotechnology 0104 chemical sciences Surfaces Coatings and Films Caking chemistry Chemical engineering lcsh:TA1-2040 visual_art visual_art.visual_art_medium ammonium nitrate Composition (visual arts) Gas chromatography–mass spectrometry 0210 nano-technology lcsh:Engineering (General). Civil engineering (General) |
| Zdroj: | Coatings, Vol 10, Iss 1093, p 1093 (2020) Coatings Volume 10 Issue 11 |
| ISSN: | 2079-6412 |
| Popis: | Ammonium nitrate fertilizers have a tendency to cake during storage. The aim of this study was to examine the effectiveness of organic coatings for preventing the caking of ammonium nitrate fertilizers and to assess the influence of the composition and physicochemical properties of the anti-caking agents used as coatings for fertilizers on their effectiveness. CAN (calcium ammonium nitrate) and AN (ammonium nitrate) fertilizers were coated with three anti-caking agents. A GC&ndash MS technique was used for the identification and quantitative determination of the composition of the organic coatings. The influence of the following physicochemical parameters of the preparations was assessed: density, viscosity, melting point, water content, and base number. The effectiveness of anti-caking agents was determined by measuring the force needed to crush the clumped uncoated and coated fertilizers, which were previously subjected to thermal cycles under load. Composition studies showed that all the tested preparations contained hexadecylamine and octadecylamine in comparable amounts and a slack wax. The results demonstrate that the key parameters of an effective anti-caking agent are low water content, appropriate viscosity, and appropriate content of fatty amines. This study can facilitate the development of innovative coatings with similar or higher efficiency, yet with a reduced negative impact on the environment. |
| Databáze: | OpenAIRE |
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