Pyrimidoquinazolinophenanthroline Opens Next Chapter in Design of Bridging Ligands for Artificial Photosynthesis**
Autor: | Jannik Brückmann, Carolin Müller, Tamar Maisuradze, Alexander K. Mengele, Djawed Nauroozi, Sven Fauth, Andreas Gruber, Stefanie Gräfe, Kerstin Leopold, Stephan Kupfer, Benjamin Dietzek‐Ivanšić, Sven Rau |
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Rok vydání: | 2022 |
Předmět: | |
Zdroj: | Chemistry – A European Journal. 28 |
ISSN: | 1521-3765 0947-6539 |
Popis: | The synthesis and detailed characterization of a new Ru polypyridine complex containing a heteroditopic bridging ligand with previously unexplored metal-metal distances is presented. Due to the twisted geometry of the novel ligand, the resultant division of the ligand in two distinct subunits leads to steady state as well as excited state properties of the corresponding mononuclear Ru(II) polypyridine complex resembling those of prototype [Ru(bpy) |
Databáze: | OpenAIRE |
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