Structure and Morphology of Silica-Reinforced Polypropylene Composites modified with m-EPR Copolymers
| Autor: | Mirela Leskovac, Iztok Švab, Matjaž Denac, Ivan Šmit, Anđela Pustak, Vojko Musil |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Materials science
Morphology (linguistics) Polymers and Plastics Organic Chemistry Nucleation Context (language use) 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Elastomer 01 natural sciences Polypropylene composites Morphology Interfacial properties Structure-property relationship 0104 chemical sciences Crystallinity Spherulite Tacticity Materials Chemistry Copolymer Composite material 0210 nano-technology |
| DOI: | 10.1007/s10965-016-0927-3 |
| Popis: | The effects of different silica (SiO2) types and different contents of two metallocene propylene-based m-EPR elastomers (differing in molecular weight and viscosity) on interfacial properties, structure and morphology of isotactic polypropylene/SiO2/m-EPR composites were investigated. Four silica fillers differing in size (nano- vs. micro-) and surface properties (hydrophilic vs. hydrophobic i.e. polar vs. non-polar) were chosen and added in 4 vol% to isotactic polypropylene. The m-EPR elastomers were added to iPP/SiO2 96/4 composites as possible impact modifier and compatibilizer at the same time in 5, 10, 15, and 20 vol% per 100 vol% of composites (phr). The investigation confirmed the overall prevailing of separated morphology of ternary iPP/SiO2/m-EPR composites, i.e. selectivity of dispersed m-EPR and silica particles toward iPP matrix as was predicted on the basis of adhesion properties. The increase of crystallinity degree and spherulite size with addition of m-EPR elastomers indicated significant solidification effect of added elastomers in addition to opposite nucleation effect of silica particles owing to surface character of filler. The effects of different silica fillers and different contents of two m-EPR elastomers were discussed within the context of morphology/structure-adhesion property relationships of the iPP/SiO2/m-EPR composites. |
| Databáze: | OpenAIRE |
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