Fine-Tuning of Boron Complexes with Cage-Shaped Ligand Geometry: Rational Design of Triphenolic Ligand as a Template for Structure Control

Autor:	Sachiko Yoshioka, Makoto Yasuda, Hideto Nakajima, Kouji Chiba, Akio Baba
Rok vydání:	2008
Předmět:	Silicon Ligand Organic Chemistry Rational design chemistry.chemical_element Biochemistry Physics::Fluid Dynamics Metal Crystallography chemistry visual_art Atom Physics::Atomic and Molecular Clusters visual_art.visual_art_medium Physical and Theoretical Chemistry Cage Boron Carbon
Zdroj:	Organic Letters. 10:929-932
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol7030944
Popis:	Boron complexes surrounded with organic cages were controlled precisely by a remote atom placed at the bottom of the cage. A replacement of the bottom tether atom (carbon or silicon) changed the characteristics (kinetic and thermodynamic factors) of boron complexes by geometric effects. A theoretical study shows that the bottom atoms also control eigenvalues of MO. This cage complex will provide a systematic template for fine-tuning of metal complexes to create various properties.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6916e57d6ad580ff19dbfc9e98afe959 https://doi.org/10.1021/ol7030944 Zobrazit plný text záznamu