Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-TrimethoxyN(2-hydroxybenzylidene) aniline

Autor:	Estienne Jacques, Kodjo Charles Guillaume, Zabri Herve, Benie Anoubile
Rok vydání:	2009
Předmět:	Infrared spectroscopy General Chemistry Electron spectroscopy lcsh:Chemistry chemistry.chemical_compound Photochromism Crystallography Aniline lcsh:QD1-999 chemistry Proton NMR Orthorhombic crystal system Spectroscopy Single crystal
Zdroj:	E-Journal of Chemistry, Vol 6, Iss 4, Pp 1103-1108 (2009)
ISSN:	2090-9810 0973-4945
DOI:	10.1155/2009/473124
Popis:	3,4,5-TrimethoxyN-(salicylidene) aniline was synthesized and characterized by IR spectroscopy,1H NMR and x-ray single crystal analysis. UV-visible spectroscopy was used for physicochemical tests. X-ray data reveals that the crystalline network cohesion of this compound is essentially assured by CH/pi type hydrogen bounds. It crystallized in the orthorhombic Pbcn space group. Electronic spectroscopy shows that the title compound doesn't present photochromic property but thermochromic one. Intermolecular interactions analysis confirms for this compound a thermochromic structural predisposition.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::67d99b7af0a2f5bdf3daf7a6a52a7993 https://doi.org/10.1155/2009/473124 Zobrazit plný text záznamu Plný text ve formátu PDF