Tin electrodeposition from sulfate solution containing a benzimidazolone derivative
| Autor: | Mohammed Cherkaoui, Said Bakkali, A. Benabida |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Scanning electron microscope
Inorganic chemistry chemistry.chemical_element 02 engineering and technology General Chemistry Overpotential 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Anode lcsh:Chemistry chemistry.chemical_compound lcsh:QD1-999 chemistry Gravimetric analysis Cyclic voltammetry Sulfate 0210 nano-technology Tin Derivative (chemistry) |
| Zdroj: | Mediterranean Journal of Chemistry, Vol 6, Iss 2, Pp 15-22 (2016) |
| ISSN: | 2028-3997 |
| DOI: | 10.13171/mjc61/01611211149/bakkali |
| Popis: | Tin electrodeposition in an acidic medium in the presence of N,N’-1,3-bis-[N-3-(6-deoxy-3-O-methyl-D-glucopyranose-6-yl)-2-oxobenzimidazol-1-yl)]-2-tetradecyloxypropane as an additive was investigated in this work. The adequate current density and the appropriate additive concentration were determined by gravimetric measurements. Chronopotentiometric curves showed that the presence of the additive caused an increase in the overpotential of tin reduction. The investigations by cyclic voltammetry technique revealed that, in the presence and in absence of the additive, there were two peaks, one in the cathodic side attributed to the reduction of Sn2+ and the other one in the anodic side assigned to the oxidation of tin previously formed during the cathodic scan. The surface morphology of the tin deposits was studied by scanning electron microscopy (SEM) and XRD. |
| Databáze: | OpenAIRE |
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