Hydrogen-like Wannier-Mott Excitons in Single Crystal of Methylammonium Lead Bromide Perovskite
| Autor: | Dmitry N. Dirin, Jenya Tilchin, Efrat Lifshitz, Maksym V. Kovalenko, Georgy I. Maikov, Aldona Sashchiuk |
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| Rok vydání: | 2016 |
| Předmět: |
Condensed Matter::Quantum Gases
Photoluminescence Condensed Matter::Other Chemistry Exciton Binding energy General Engineering General Physics and Astronomy 02 engineering and technology Condensed Matter::Mesoscopic Systems and Quantum Hall Effect 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Molecular physics 0104 chemical sciences Crystal Condensed Matter::Materials Science General Materials Science Atomic physics 0210 nano-technology Single crystal Biexciton Bohr radius Perovskite (structure) |
| Zdroj: | ACS nano. 10(6) |
| ISSN: | 1936-086X |
| Popis: | A thorough investigation of exciton properties in bulk CH3NH3PbBr3 perovskite single crystals was carried out by recording the reflectance, steady-state and transient photoluminescence spectra of submicron volumes across the crystal. The study included an examination of the spectra profiles at various temperatures and laser excitation fluencies. The results resolved the first and second hydrogen-like Wannier–Mott exciton transitions at low temperatures, from which the ground-state exciton’s binding energy of 15.33 meV and Bohr radius of ∼4.38 nm were derived. Furthermore, the photoluminescence temperature dependence suggested dominance of delayed exciton emission at elevated temperatures, originating from detrapping of carriers from shallow traps or/and from retrapping of electron–hole pairs into exciton states. The study revealed knowledge about several currently controversial issues that have an impact on functionality of perovskite materials in optoelectronic devices. |
| Databáze: | OpenAIRE |
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