Determination of Hyperpolarizability Tensor Components by Depolarized Hyper Rayleigh Scattering

Autor: A.G.T. Ruiter, N.F. van Hulst, B. Bölger, G.J.T. Heesink
Přispěvatelé: Optical Sciences
Rok vydání: 1993
Předmět:
Zdroj: MESA Dag 1993
Physical review letters, 71(7), 999-1002. American Physical Society
ISSN: 0031-9007
Popis: Depolarized hyper Rayleigh scattering of para-nitroaniline (C2v symmetry) and nitrocalix[4]arene (C4v symmetry) in solution has been measured. Using linearly and circularly polarized fundamental radiation information about the ratios between the several hyperpolarizability tensor components, including their sign, was obtained. Results are consistent with the theory developed for both symmetry groups. Comparison between experimental depolarization ratios and ratios obtained from ab initio calculated hyperpolarizability tensor components shows good agreement.
Databáze: OpenAIRE