Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine–dioxime catalysts under both aqueous and organic conditions
| Autor: | Wai-Lun Man, Shek-Man Yiu, Shun Cheung Cheng, Chi-Fai Leung, Pui Yu Ho, Chi-Chiu Ko, Marc Robert, Chun Leung Kwok, Po Keung Tsang, Vonika Ka-Man Au |
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| Rok vydání: | 2020 |
| Předmět: |
Aqueous solution
Metals and Alloys chemistry.chemical_element Precious metal General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal chemistry.chemical_compound chemistry visual_art Materials Chemistry Ceramics and Composites Photocatalysis visual_art.visual_art_medium Cobalt Derivative (chemistry) Diimine Nuclear chemistry |
| Zdroj: | Chemical Communications. 56:7491-7494 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino–dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively. |
| Databáze: | OpenAIRE |
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