Synthesis and characterization of arginine-doped heliotrope leaves with high clean-up capacity for crystal violet dye from aqueous media
| Autor: | Yassine Naciri, Khalihana H'Maida, Bahcine Bakiz, Mohamed Arahou, Abdallah Albourine, Mohammed Fekhaoui, Zeeshan Ajmal, Abdelghani Hsini, Lahoucine Brini, Asmae Bouziani, Aziz Boulahya |
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| Přispěvatelé: | OpenMETU |
| Rok vydání: | 2021 |
| Předmět: |
Thermogravimetric analysis
Environmental Engineering Scanning electron microscope Arginine Environmental technology. Sanitary engineering thermodynamic symbols.namesake chemistry.chemical_compound Adsorption Differential scanning calorimetry Crystal violet Fourier transform infrared spectroscopy TD1-1066 Water Science and Technology arg-heliotrope leaves Aqueous solution Chemistry isotherm Langmuir adsorption model Hydrogen-Ion Concentration Plant Leaves adsorption kinetics symbols Thermodynamics Gentian Violet Water Pollutants Chemical Nuclear chemistry |
| Zdroj: | Water Science and Technology, Vol 84, Iss 9, Pp 2265-2277 (2021) |
| ISSN: | 1996-9732 0273-1223 |
| Popis: | A novel arginine-modified Heliotrope leaf (Arg@HL) was used as adsorbent for the crystal violet (CV) dye adsorption in a batch process. The physicochemical and morphological composition of Arg@HL were characterized by field-emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The experiments were carried out to investigate the factors that influence the dye uptake by the adsorbent, such as the contact time under agitation, adsorbent amount, initial dye concentration, temperature and pH of dye solution. The optimum conditions of adsorption were found on the batch scale as followed: CV concentration of 20 mg·L−1, an amount of 0.75 g·L−1 of the adsorbent, 90 min contact time, 6 pH and 25 °C temperature for Arg@HL. The results confirmed a second-order model explaining the dye crystal violet's adsorption's kinetics by Arg-Heliotrope leaves. The Langmuir model effectively defines the adsorption isotherms. The results revealed that the Arg@HL has the potential to be used as a low-cost adsorbent for the removal of CV dye from aqueous solutions. HIGHLIGHTS The first effort to use a low-cost arginine-modified Heliotrope leaves material as an adsorbent for crystal dye elimination by adsorption procedures.; CV dye was efficiently removed using Arg@HL.; Arg@HL exhibited high adsorption capacity for CV dye.; Adsorption process follows the Langmuir isotherm. |
| Databáze: | OpenAIRE |
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