Understanding the Stabilizing Effects of Nanoscale Metal Oxide and Li-Metal Oxide Coatings on Lithium-Ion Battery Positive Electrode Materials
Autor: | Yao Lide, Timo Kankaanpää, Seyedabolfazl Mousavihashemi, Miia Mäntymäki, Zahra Ahaliabadeh, Tanja Kallio, Jouko Lahtinen, Ville Miikkulainen, Kenichiro Mizohata, Hua Jiang |
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Přispěvatelé: | Department of Chemistry and Materials Science, University of Helsinki, Department of Applied Physics, Umicore Finland, Aalto-yliopisto, Aalto University, Department of Chemistry, Materials Physics |
Rok vydání: | 2021 |
Předmět: |
Materials science
SURFACE 116 Chemical sciences NICKEL Oxide Nanotechnology titanium oxide 02 engineering and technology 010402 general chemistry 01 natural sciences Lithium-ion battery Metal chemistry.chemical_compound Atomic layer deposition Ni-rich positive electrode NANOPARTICLES General Materials Science SDG 7 - Affordable and Clean Energy Lithium titanate Nanoscopic scale RICH Electrode material ENHANCED ELECTROCHEMICAL PERFORMANCE AL2O3 electrode coating DEGRADATION 021001 nanoscience & nanotechnology CATHODE MATERIALS 0104 chemical sciences Titanium oxide chemistry ALD visual_art visual_art.visual_art_medium LINI0.8CO0.1MN0.1O2 0210 nano-technology ATOMIC LAYER DEPOSITION lithium titanate |
Zdroj: | Ahaliabadeh, Z, Miikkulainen, V, Mäntymäki, M, Mousavihashemi, S, Lahtinen, J, Lide, Y, Jiang, H, Mizohata, K, Kankaanpää, T & Kallio, T 2021, ' Understanding the Stabilizing Effects of Nanoscale Metal Oxide and Li–Metal Oxide Coatings on Lithium-Ion Battery Positive Electrode Materials ', ACS Applied Materials & Interfaces, vol. 13, no. 36, pp. 42773-42790 . https://doi.org/10.1021/acsami.1c11165 |
ISSN: | 1944-8252 |
Popis: | Funding Information: This work made use of the Aalto University Otanano and RAMI infrastructures. The authors also thank Dr. Hannu Revitzer for performing AAS measurements. Financial support from Business Finland BATCircle (Energy) (no. 2117574) is also greatly acknowledged. Publisher Copyright: © 2021 The Authors. Published by American Chemical Society. Nickel-rich layered oxides, such as LiNi0.6Co0.2Mn0.2O2 (NMC622), are high-capacity electrode materials for lithium-ion batteries. However, this material faces issues, such as poor durability at high cut-off voltages (>4.4 V vs Li/Li+), which mainly originate from an unstable electrode-electrolyte interface. To reduce the side reactions at the interfacial zone and increase the structural stability of the NMC622 materials, nanoscale ( |
Databáze: | OpenAIRE |
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