Synthesis, characterization and computational investigation of poly(styrene-co-1-methylpyrenyl methacrylate): its efficiency as a macrophotoinitiator
| Autor: | Hakan Akat, Armagan Kinal, Fehmi Saltan, Berna Körpınar |
|---|---|
| Přispěvatelé: | Ege Üniversitesi |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
Polymers and Plastics General Chemical Engineering Radical polymerization 02 engineering and technology 010402 general chemistry Methacrylate 01 natural sciences Analytical Chemistry Styrene chemistry.chemical_compound Polymer chemistry Side chain Macrophotoinitiator pyrene poly(methyl methacrylate) 021001 nanoscience & nanotechnology radical polymerization Poly(methyl methacrylate) 0104 chemical sciences Photopolymer chemistry visual_art photopolymerization visual_art.visual_art_medium Pyrene 0210 nano-technology |
| Zdroj: | International Journal of Polymer Analysis and Characterization. 25:134-146 |
| ISSN: | 1563-5341 1023-666X |
| DOI: | 10.1080/1023666x.2020.1766787 |
| Popis: | In this study, it has been demonstrated that poly(styrene-co-1-methylpyrenyl methacrylate) macro-photoinitiator (PSMM) containing side chain pyrene moieties were successfully prepared using "radical polymerization method." Firstly, 1-pyrene methanol and methacryloyl chloride were reacted in dichloromethane for 24 h at 0 degrees C in order to give 1-methoxy pyrene methacrylate macromonomer. Then styrene was polymerized with this macromonomer to obtained macro-photoinitiator. the synthesized copolymer is also both computationally and experimentally demonstrated that the macro-photoinitiator obtained has similar absorption characteristics with the parent pyrene molecule. According to obtained results, the synthesized copolymer was more effective in the presence of triethyl amine as a macro-photoinitiator. |
| Databáze: | OpenAIRE |
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