MoO 2 Nanowire Electrochemically Decorated Graphene Additively Manufactured Supercapacitor Platforms

Autor: Craig E. Banks, Samuel J. Rowley-Neale, Alejandro García-Miranda Ferrari, Michael P. Down, Jessica L. Pimlott
Rok vydání: 2021
Předmět:
Zdroj: Advanced Energy Materials. 11:2102514
ISSN: 1614-6840
1614-6832
DOI: 10.1002/aenm.202102514
Popis: Additively manufactured (AM) supercapacitor platforms are fabricated from bespoke filaments, which are comprised of electro-conductive graphene (20 wt%) incorporated polylactic acid (80 wt%), via fused deposition modeling and denoted as G/AMEs. The G/AMEs are shown to be capable of acting as a template for the electrodeposition of metals/metal oxides, in particular MoO2 nanowires (MoO2-G/AMEs), which are subsequently explored as a capacitor within 1 m H2SO4, 1-butyl-3-methylimidazolium hexafluorophosphate, and 1-butyl-3-methylimidazolium tetrafluoroborate. Optimization of the MoO2-G/AMEs demonstrates capacitance up to 1212 F g–1 when used in a symmetric arrangement. The material science described herein represents a significant enhancement in unlocking AMs potential as a valid manufacturing route for device level capacitance architectures.
Databáze: OpenAIRE