MoO 2 Nanowire Electrochemically Decorated Graphene Additively Manufactured Supercapacitor Platforms
Autor: | Craig E. Banks, Samuel J. Rowley-Neale, Alejandro García-Miranda Ferrari, Michael P. Down, Jessica L. Pimlott |
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Rok vydání: | 2021 |
Předmět: | |
Zdroj: | Advanced Energy Materials. 11:2102514 |
ISSN: | 1614-6840 1614-6832 |
DOI: | 10.1002/aenm.202102514 |
Popis: | Additively manufactured (AM) supercapacitor platforms are fabricated from bespoke filaments, which are comprised of electro-conductive graphene (20 wt%) incorporated polylactic acid (80 wt%), via fused deposition modeling and denoted as G/AMEs. The G/AMEs are shown to be capable of acting as a template for the electrodeposition of metals/metal oxides, in particular MoO2 nanowires (MoO2-G/AMEs), which are subsequently explored as a capacitor within 1 m H2SO4, 1-butyl-3-methylimidazolium hexafluorophosphate, and 1-butyl-3-methylimidazolium tetrafluoroborate. Optimization of the MoO2-G/AMEs demonstrates capacitance up to 1212 F g–1 when used in a symmetric arrangement. The material science described herein represents a significant enhancement in unlocking AMs potential as a valid manufacturing route for device level capacitance architectures. |
Databáze: | OpenAIRE |
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