One-Pot Synthesis of Substituted Styrenes from Vicinal Dibromoalkanes and Arylboronic Acids

Autor: A. A. Tikhonov, M. V. Chirskaya, Marina I. Struchkova, N. L. Merkulova, S. G. Zlotin, Andrei A. Vasil'ev
Rok vydání: 2007
Předmět:
Zdroj: ChemInform. 38
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200744038
Popis: Dehydrobromination of vicinal dibromoalkanes in systems comprising 1,2-dimethoxy-ethane, N-butyl-N′-methylimidazolium tetrafluoroborate (or tetrabutylammonium bromide), and a base with subsequent palladium-catalyzed cross-coupling of the thus formed bromoalkenes with arylboronic acids furnished substituted styrenes.
Databáze: OpenAIRE