Effects of irradiation on the mechanisms controlling the residual rate of an alumino-borosilicate glass

Autor: Gin, Stephane, Jegou, Christophe, Sessegolo, Loryelle, Bisbrouck, Nicolas, Jan, Amreen, Chartier, Myriam, Tribet, Magaly, Delaye, Jean-Marc, Angeli, Frederic
Přispěvatelé: Laboratoire d'Etudes du Comportement à Long Terme des matériaux de conditionnement (LCLT), Département de recherche sur les Procédés et Matériaux pour les Environnements complexes (DPME), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: npj Materials Degradation
npj Materials Degradation, 2022, 6, pp.1-14. ⟨10.1038/s41529-022-00266-w⟩
ISSN: 2397-2106
Popis: The alteration of a four-oxide alumino-borosilicate glass close to International Simple Glass (ISG) was studied in Si saturation conditions at pH 3, pH 7, and pH 9 using solution and post mortem solid analyses. In particular, the study examined the impact of structural disorder on the glass alteration generated by swift heavy ion irradiation. It is shown that the pre-irradiated glass altered three to four times more than the non-irradiated glass, depending on the pH. This increased alteration can be attributed to two factors: an increased hydrolysis speed of the Si–O–B bonds, which control the glass dissolution under these Si saturation conditions, and a less passivating alteration layer. The latter effect suggests that the glass structural disorder is retained by the first gel formed, which means very low Si atom mobility during alteration. However, gel maturation tends to mitigate the detrimental effect of radiation damages. These results will contribute to the development of a predictive residual rate model.
Databáze: OpenAIRE
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