Palladium-Catalyzed 4-Fold Domino Reaction for the Synthesis of a Polymeric Double Switch
| Autor: | Torsten Fornefeld, Taukeer A. Khan, Dennis Hübner, Lutz F. Tietze, Philipp Vana |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Acrylate 010405 organic chemistry Chemistry Alkene Butyl acrylate Organic Chemistry Chain transfer 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Catalysis chemistry.chemical_compound Polymerization Cascade reaction Polymer chemistry Moiety Physical and Theoretical Chemistry |
| Zdroj: | Organic letters. 20(7) |
| ISSN: | 1523-7052 |
| Popis: | A palladium-catalyzed 4-fold domino reaction consisting of two carbopalladation reactions and two C–H activation reactions, followed by the introduction of an acrylate moiety, led to the tetra-substituted helical alkene A2, using the dialkyne A3 as a substrate. The alkene was copolymerized with butyl acrylate by using the reversible addition–fragmentation chain transfer polymerization (RAFT) to give the desired polymeric switch A1. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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