Preparation of partially benzylated mono-, di-, and trisaccharides by selective cleavage of the β-fructofuranosidic linkage in fully benzylated sucrose and sucrose-related oligosaccharides under acidic conditions
| Autor: | Sho Matsuda, Noriko Misawa, Takashi Yamanoi, Mikio Watanabe |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
Sucrose
Anomer Molecular Sequence Data Fructose Disaccharides Biochemistry Analytical Chemistry Stachyose chemistry.chemical_compound Benzyl Compounds Carbohydrate Conformation Organic chemistry Raffinose Aqueous solution Hydrolysis Monosaccharides Organic Chemistry Silver Compounds Oxides Melezitose General Medicine Hydrogen-Ion Concentration Sodium Compounds Selective cleavage Carbohydrate Sequence chemistry Trisaccharides |
| Zdroj: | Carbohydrate Research. 343:1366-1372 |
| ISSN: | 0008-6215 |
| DOI: | 10.1016/j.carres.2008.03.024 |
| Popis: | Several partially benzylated mono-, di-, and trisaccharides having an anomeric hydroxyl group were successfully prepared by selective cleavage of the β-fructofuranosidic linkage in fully benzylated sucrose and sucrose-related oligosaccharides derived from lactosucrose, raffinose, melezitose, stachyose, and nystose under acidic conditions using 1:10 75% aqueous sulfuric acid–dioxane at room temperature for 1 h. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect