Degradation of carbamazepine over MOFs derived FeMn@C bimetallic heterogeneous electro-Fenton catalyst
| Autor: | Yang Zheng, Xuedong Du, Ge Song, Jinyu Gu, Jieru Guo, minghua zhou |
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| Rok vydání: | 2022 |
| Předmět: |
History
Environmental Engineering Polymers and Plastics Health Toxicology and Mutagenesis Public Health Environmental and Occupational Health General Medicine General Chemistry Pollution Industrial and Manufacturing Engineering Catalysis Carbon Electrolysis Benzodiazepines Carbamazepine Environmental Chemistry Business and International Management |
| Zdroj: | Chemosphere. 312(Pt 2) |
| ISSN: | 1879-1298 |
| Popis: | A highly efficient heterogeneous electro-Fenton (Hetero-EF) catalyst with core-shell structure was successfully prepared by calcination of Mn-doped Mil-53 (Fe) precursor at high temperature. FeMn@C-800/2 prepared at pyrolysis temperature of 800 °C and Fe:Mn molar doping ratio of 2:1 showed the best catalytic performance for the degradation of carbamazepine (CBZ). The characterization, properties and stability of FeMn@C-800/2 were systematically investigated, obtaining the apparent first-order reaction rate of Hetero-EF was 8.9 and 17.8 times higher than that on Fe@C-800 and Mn@C-800 at the optimized conditions of current density 10 mA cm |
| Databáze: | OpenAIRE |
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