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The treatment of nuclear wastewater is one of the most urgent and arduous tasks currently, but traditional adsorption materials are significantly limited in practice due to their high demands on auxiliary operations (e.g., shaking or centrifugation) caused by poor stability or recyclability. To tackle this challenge, a water-based ferrofluid composed of magnetic nanoparticles grown in polyethylenimine branches is reported and applied to nuclear wastewater treatment. It is demonstrated that the ferrofluid can keep stable spontaneously in a wide pH range (3-11) out of their ultra-small size, strong electropositivity as well as high charge buffering capacity to achieve shaker-free adsorption, and can be magnetically separated after the neutralization of their positive charge to achieve convenient recycle. Meanwhile, it is found that the ferrofluid shows wide pH/adsorbate applicability and strong ion selectivity in radionuclides absorption. Furthermore, it is anticipated to achieve maximum adsorption capacities for U(VI), Sr(II) and Co(II) as high as 331.5, 427.8 and 759.6 mg/g, respectively. With these characteristics, this ferrofluid outperforms other reported adsorbents. In conclusion, this work provides a practical and effective radioactive wastewater treatment strategy, and enlightens the development of materials for other applications facing the dilemma of incompatible stability and recyclability. |
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