(1E)-2-(Diacetylamino)-1-methylprop-1-enyl acetate

Autor:	Marcus R. Bond, Bjorn Olesen
Rok vydání:	2003
Předmět:	chemistry.chemical_classification Alanine Double bond Molecular Structure Chemistry Stereochemistry Pyridines Stereoisomerism General Medicine Crystal structure Acetates Hyperconjugation Crystallography X-Ray General Biochemistry Genetics and Molecular Biology
Zdroj:	Acta crystallographica. Section C, Crystal structure communications. 60(Pt 3)
ISSN:	0108-2701
Popis:	The analysis of the title compound, C 10 H 15 NO 4 , firmly establishes the configuration of the double bond as E, a stereochemistry that had been assigned tentatively by other methods. The diacetylamine and acetate substituents are approximately coplanar to one another, but approximately perpendicular to the planar ethene core. H atoms of the ethene methyl substituents are found within the ethene plane, indicating that hyperconjugation does not play an important role in stabilizing the double bond.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4a844a9302ded3e8566837f8f54a0b62 https://pubmed.ncbi.nlm.nih.gov/15004381 Zobrazit plný text záznamu Plný text