Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands
| Autor: | Eiad Saif, Necmi Dege, Adnan M. Qadir, Li Yongxin, Sevgi Kansiz |
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| Přispěvatelé: | School of Physical and Mathematical Sciences |
| Rok vydání: | 2021 |
| Předmět: |
crystal structure
Denticity Stacking chemistry.chemical_element Crystal structure 010402 general chemistry 010403 inorganic & nuclear chemistry Ring (chemistry) 01 natural sciences Research Communications chemistry.chemical_compound Chemistry [Science] General Materials Science Crystallography Hydrogen bond Ligand Hirshfeld surface 2-nitrobenzoate General Chemistry Tetramethylethylenediamine Condensed Matter Physics Copper 0104 chemical sciences Copper(II) chemistry tetramethylethylenediamine QD901-999 Crystal Structure copper(II) tetramethylethylenediamine 2-nitrobenzoate |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications Acta Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 4, Pp 412-415 (2021) |
| ISSN: | 2056-9890 |
| DOI: | 10.1107/s2056989021002802 |
| Popis: | In the title complex, [Cu(2-nitrobenzoate)2(tmeda)], the central metal atom has distorted square-planar geometry with one oxygen atom each from two 2-nitrobenzoate ligands and two TMEDA ligand nitrogen atoms. The reaction of copper(II) sulfatepentahydrate with 2-nitrobenzoic acid and N,N,N′,N′-tetramethylethylenediamine (TMEDA) in basic solution produces the complex bis(2-nitrobenzoato-κO)(N,N,N′,N′-tetramethylethylenediamine-κ2 N,N′)copper(II), [Cu(C7H4NO4)2(C6H16N2)] or [Cu(2-nitrobenzoate)2(tmeda)]. Each carboxylate group of the 2-nitrobenzoate ligand is coordinated by CuII atom in a monodentate fashion and two TMEDA ligand nitrogen atoms are coordinate by the metal center, giving rise to a distorted square-planar coordination environment. In the crystal, metal complexes are linked by centrosymmetric C—H⋯O hydrogen bonds, forming ribbons via a R 2 2(10) ring motif. These ribbons are linked by further C—H⋯O hydrogen bonds, leading to two-dimensional hydrogen-bonded arrays parallel to the bc plane. Weak π–π stacking interactions provide additional stabilization of the crystal structure. Hirshfeld surface analysis, dnorm and two-dimensional fingerprint plots were examined to verify the contributions of the different intermolecular contacts within the supramolecular structure. The major interactions of the complex are O⋯H/H⋯O (44.9%), H⋯H (34%) and C⋯H (14.5%). |
| Databáze: | OpenAIRE |
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