Phase- and Size-Controlled Synthesis of Hexagonal and Cubic CoO Nanocrystals

Autor:	Jae Ha Shim, Nam Hwi Hur, Sang Jun Oh, Won Seok Seo, Eunkwang Lee, Joon T. Park
Rok vydání:	2005
Předmět:	Thermal decomposition Nanoparticle Crystal growth General Chemistry Biochemistry Catalysis Crystal Condensed Matter::Materials Science Crystallography chemistry.chemical_compound Colloid and Surface Chemistry chemistry Nanocrystal Oleylamine Phase (matter) Hydrothermal synthesis
Zdroj:	Journal of the American Chemical Society. 127:6188-6189
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja050359t
Popis:	Highly crystalline, phase- and size-controlled CoO nanocrystals of hexagonal and cubic phases have been prepared by thermal decomposition of Co(acac)3 in oleylamine under an inert atmosphere. Kinetic and thermodynamic control for the precursor formation leads to two different seeds of hexagonal and cubic phases at higher temperatures. The crystal size of both CoO phases can be easily manipulated by changing the precursor concentration and reaction temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4989f2437557d6642b76a13d77c0c74a https://doi.org/10.1021/ja050359t Zobrazit plný text záznamu