Zeolites Modified Metal Cations as Catalysts in Hydrocarbon Oxidation and the Alkyl Alcohol

Autor:	Zumrud Abdulmutallib Shabanova, Alla M. Guseynova, Agadadsh Makhmud Aliyev, Fikret Vakhid Aliyev
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Olefin fiber Ketone Ethylene oxidation Carboxylic acid aliphatic alcohols Alcohol Catalysis lcsh:Social Sciences lcsh:H chemistry.chemical_compound chemistry Organic chemistry Oxidative coupling of methane Dehydrogenation hydrocarbons metalleolitnye catalysts
Zdroj:	Evropejskij Issledovatelʹ, Vol 82, Iss 9-1, Pp 1564-1590 (2014)
ISSN:	2224-0136 2219-8229
DOI:	10.13187/er.2014.82.1564
Popis:	The results of studies on the creation of highly metalltceolitnyh systems and the study of their catalytic activities in the oxidation of lower olefin hydrocarbons (ethylene to acetaldehyde, acetone, propylene, butylene methyl ethyl ketone); aliphatic C1-C5 alcohols to their corresponding aldehydes, ketones, carboxylic acids and carboxylic acid esters; oxidative dehydrogenation of naphthenes in the alicyclic diene hydrocarbons and the oxidative dimerization of methane to acetylene. It has been established that the selectivity of these catalysts determined optimal combination of metal components with the acidity and the structure of the zeolite. Selected highly effective catalysts for the reactions studied. Based on the results of experimental studies of the kinetics of the reactions of oxidation of lower olefin hydrocarbons and aliphatic alcohols, the oxidative dehydrogenation of naphthenes and oxidative coupling of methane on the synthesized catalysts are represented by their probable stepwise mechanism and kinetic models developed reactions.
Databáze:	OpenAIRE
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