Efficient synthesis of organic semiconductors by Suzuki–Miyaura coupling in an aromatic micellar medium
| Autor: | Mauro Sassi, Luca Beverina, Chiara Ceriani, Sara Mattiello, Alessandro Sanzone, Adiel Mauro Calascibetta, Giulia Maria Garavaglia |
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| Přispěvatelé: | Sanzone, A, Mattiello, S, Maria Garavaglia, G, Calascibetta, A, Ceriani, C, Sassi, M, Beverina, L |
| Rok vydání: | 2019 |
| Předmět: |
Coupling
010405 organic chemistry Benzothiophene Conjugated system 010402 general chemistry 01 natural sciences Pollution Combinatorial chemistry 0104 chemical sciences Catalysis Organic semiconductor chemistry.chemical_compound chemistry Amphiphile Environmental Chemistry catalisi micellare semiconduttori organici green chemistry Derivative (chemistry) |
| Zdroj: | Green Chemistry. 21:4400-4405 |
| ISSN: | 1463-9270 1463-9262 |
| Popis: | Micellar catalysis enables carrying out Suzuki-Miyaura couplings in water under exceptionally mild conditions. Extension of such a protocol to the sustainable synthesis of highly conjugated, poorly soluble materials like [1]benzothieno[3,2-b][1]benzothiophene (BTBT) requires redesigning of the surfactants employed. The here reported new naphthalenediimide containing amphiphilic derivative, PiNap-750M, features unprecedented performances in the preparation of this and other relevant classes of organic semiconductors in water and at room temperature. |
| Databáze: | OpenAIRE |
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