A molecular Mo4Bi4 framework composed exclusively of unsupported metal-metal bonds
| Autor: | Christina Knispel, Carolin Tschersich, Christian Limberg |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
Stereochemistry
Metals and Alloys Substituent chemistry.chemical_element General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Bismuth chemistry.chemical_compound Crystallography Residue (chemistry) chemistry Materials Chemistry Ceramics and Composites Metal metal |
| Zdroj: | Chemical communications (Cambridge, England). 47(38) |
| ISSN: | 1364-548X |
| Popis: | Reaction of [Cp(2)MoH(2)] with bismuth allyloxide, [Bi{OCH(CH(3))CH==CH(2)}(3)], gave rise to an extended octanuclear complex wherein two cyclic Mo(2)Bi(2) units composed of four Mo-Bi bonds are linked by a Bi-Bi bond. The fact that the construction of such an assembly could be accomplished only in the case of a monomethylation of the parent allyl residue demonstrates a subtle substituent effect. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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