Pyrene-phenylglycinol linked reversible ratiometric fluorescent chemosensor for the detection of aluminium in nanomolar range and its bio-imaging
| Autor: | Manikantan Syamala Kiran, K. Velmurugan, Natarajan Duraipandy, Lijun Tang, Raju Nandhakumar, J. Prabhu, A. Raman, Shanmugam Easwaramoorthi |
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| Rok vydání: | 2019 |
| Předmět: |
Metal ions in aqueous solution
chemistry.chemical_element 02 engineering and technology Excimer Photochemistry 01 natural sciences Biochemistry Cell Line Analytical Chemistry Ion chemistry.chemical_compound Aluminium Humans Environmental Chemistry Spectroscopy Fluorescent Dyes Pyrenes Quenching (fluorescence) 010401 analytical chemistry 021001 nanoscience & nanotechnology Fluorescence 0104 chemical sciences Spectrometry Fluorescence Monomer Microscopy Fluorescence chemistry Ethanolamines Pyrene 0210 nano-technology Aluminum |
| Zdroj: | Analytica Chimica Acta. 1090:114-124 |
| ISSN: | 0003-2670 |
| DOI: | 10.1016/j.aca.2019.09.008 |
| Popis: | Pyrene-phenylglycinol tangled ratiometric sensor (R)-1 was developed for the detection of Al3+ ion over other metal ions. Ratiometric behaviour of (R)-1 for Al3+ ion explained through monomer emission and excimer quenching leads to avoiding the π-π interactions of bis-pyrene rings. Pull-push to push-pull binding mechanism is successfully explained by DFT and sensing of Al3+-ions demonstrated in living cells. The LOD of (R)-1 for Al3+ downs to nanomolar concentrations which is lower than the allowed concentration of drinking water set by the (World Health Organization) WHO. |
| Databáze: | OpenAIRE |
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