| Autor: |
Gregory S. Huff, Anna Lucia Berger, Karsten Donabauer, Stefano Crespi, Mitasree Maity, Burkhard König |
| Jazyk: |
němčina |
| Rok vydání: |
2019 |
| Předmět: |
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| Zdroj: |
Chemical Science |
| Popis: |
We present a redox-neutral method for the photocatalytic generation of carbanions. Benzylic carboxylates are photooxidized by single electron transfer; immediate CO2 extrusion and reduction of the in situ formed radical yields a carbanion capable of reacting with aliphatic aldehydes as electrophiles giving the Grignard analogous reaction product. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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