Triterpene saponins from the roots of Bupleurum spinosum Gouan
| Autor: | Chiaki Tanaka, Tomofumi Miyamoto, Anne Claire Mitaine-Offer, Dalila Smati, Thomas Paululat, Amina Dahmoune, Marie Aleth Lacaille-Dubois |
|---|---|
| Přispěvatelé: | Fonctions et dysfonctions épithéliales - UFC (EA 4267) (FDE), Université de Franche-Comté (UFC), Université Bourgogne Franche-Comté [COMUE] (UBFC)-Université Bourgogne Franche-Comté [COMUE] (UBFC) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Bupleurum biology 010405 organic chemistry Stereochemistry Plant Science biology.organism_classification Mass spectrometry 01 natural sciences Biochemistry 0104 chemical sciences 010404 medicinal & biomolecular chemistry Triterpene chemistry [CHIM]Chemical Sciences Stratum spinosum Agronomy and Crop Science Two-dimensional nuclear magnetic resonance spectroscopy Heteronuclear single quantum coherence spectroscopy Biotechnology |
| Zdroj: | Phytochemistry Letters Phytochemistry Letters, 2020, 39, pp.157-161. ⟨10.1016/j.phytol.2020.08.007⟩ |
| ISSN: | 1874-3900 |
| DOI: | 10.1016/j.phytol.2020.08.007⟩ |
| Popis: | Three previously undescribed triterpene saponins, and four known ones, were isolated from the EtOH/H2O extract of the roots of Bupleurum spinosum. Their structures were characterized using spectroscopic techniques including 1D and 2D NMR (1H, 13C, COSY, TOCSY, ROESY, HSQC, and HMBC) experiments and mass spectrometry as 3-O-β-D-glucopyranosyl-(1→6)-[β-D-glucopyranosyl-(1→2)]-[α-L-rhamnopyranosyl-(1→4)]-β-D-glucopyranosyl-3β,16β,23,28-tetrahydroxyolean-12-ene, 3-O-β-D-glucopyranosyl-(1→6)-[β-D-glucopyranosyl-(1→2)]-[α-L-rhamnopyranosyl-(1→4)]-β-D-glucopyranosyl-3β,16β,28-trihydroxy-23-oxoolean-12-ene, 3-O-β-D-glucopyranosyl-(1→6)-[α-L-rhamnopyranosyl(1→4)]-β-D-glucopyranosyl-3β,16β,28-trihydroxyolean-12-ene-23-oic-acid. The chemotaxonomic significance is underlined. |
| Databáze: | OpenAIRE |
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