| Autor: |
Csaba Fábri, Gábor J. Halász, Ágnes Vibók |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
The Journal of Physical Chemistry Letters. 13:1172-1179 |
| ISSN: |
1948-7185 |
| DOI: |
10.1021/acs.jpclett.1c03465 |
| Popis: |
The interaction of a molecule with the quantized electromagnetic field of a nanocavity gives rise to light-induced conical intersections between polaritonic potential energy surfaces. We demonstrate for a realistic model of a polyatomic molecule that the time-resolved ultrafast radiative emission of the cavity enables following both nuclear wavepacket dynamics on, and nonadiabatic population transfer between, polaritonic surfaces without applying a probe pulse. The latter provides an unambiguous (and in principle experimentally accessible) dynamical fingerprint of light-induced conical intersections. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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