Asymmetric Michael addition of trisubstituted carbanion to nitroalkenes catalyzed by sodium demethylquinine salt in water
| Autor: | Rui Wang, Qian Liu, Fu-Xin Chen, Pin Gong, Chunliang Liu, Cheng Shao |
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| Rok vydání: | 2008 |
| Předmět: |
Salt (chemistry)
Alkenes Crystallography X-Ray Medicinal chemistry Catalysis Analytical Chemistry Substrate Specificity Nucleophile Drug Discovery Organic chemistry Spectroscopy Carbanion Pharmacology chemistry.chemical_classification Quinine Organic Chemistry Enantioselective synthesis Water Stereoisomerism Carbon chemistry Organocatalysis Michael reaction Salts Chirality (chemistry) |
| Zdroj: | Chirality. 21(6) |
| ISSN: | 1520-636X |
| Popis: | A mild method for the asymmetric synthesis of quaternary and tertiary carbon centers has been developed through Michael addition of trisubstituted carbon nucleophile to nitroalkenes catalyzed by low loading sodium demethylquinine salt in water. Chirality, 2008. © 2009 Wiley-Liss, Inc. |
| Databáze: | OpenAIRE |
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