Evolved Gas Analysis‐Mass Spectrometry to Identify the Earliest Organic Binder in Aegean Style Wall Paintings
| Autor: | Austin Nevin, Leila Birolo, Ilaria Bonaduce, Georgia Ntasi, Anna Lluveras-Tenorio, Assaf Yasur-Landau, Ravit Linn, Eric H. Cline |
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| Přispěvatelé: | Linn, Ravit, Bonaduce, Ilaria, Ntasi, Georgia, Birolo, Leila, Yasur-Landau, Assaf, Cline, Eric H, Nevin, Austin, Lluveras-Tenorio, Anna |
| Jazyk: | angličtina |
| Předmět: |
Bronze Age
organic binders Evolved gas analysis media_common.quotation_subject Mass spectrometry 01 natural sciences Catalysis Aegean style painting Egyptian blue chemistry.chemical_compound evolved gas analysis 0601 history and archaeology media_common mass spectrometry Painting 060102 archaeology Chemistry (all) 010401 analytical chemistry General Medicine Art 06 humanities and the arts General Chemistry evolved gas analysi Archaeology humanities 0104 chemical sciences Style (visual arts) Eastern mediterranean chemistry Aegean style paintings |
| Zdroj: | Angewandte Chemie International Edition |
| ISSN: | 1521-3773 1433-7851 |
| DOI: | 10.1002/anie.201806520 |
| Popis: | An organic binder was identified in the painted fragments from the Canaanite palace of Tel Kabri, Israel. Recently dated to the late 18th century B.C.E. by 14 C, Tel Kabri is the most ancient of the Eastern Mediterranean sites in which Aegean style paintings have been found. The application of pigments was suspected to be using an organic binding medium, particularly for the Egyptian Blue pigment. Samples of blue paint were examined using evolved gas analysis-mass spectrometry (EGA-MS) in order to overcome the analytical challenges imposed by highly degraded aged proteinaceous materials. Egg was identified as the binder based on the presence of hexadecanonitrile and octadecanonitrile, confirming the use of a secco painting technique. Lysozyme C from Gallus gallus was detected by proteomics analysis, confirming the presence of egg. To our knowledge, this is the earliest use of egg as a binder in Aegean style wall paintings. |
| Databáze: | OpenAIRE |
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