An Electron-Transfer Series of High-Valent Chromium Complexes with Redox Non-Innocent, Non-Heme Ligands
| Autor: | Connie C. Lu, Karl Wieghardt, Eckhard Bill, Eberhard Bothe, Serena DeBeer George, Thomas Weyhermüller |
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| Rok vydání: | 2008 |
| Předmět: |
Chromium
Free Radicals Ligand Radical Inorganic chemistry Center (category theory) chemistry.chemical_element Bioinorganic chemistry General Chemistry Heme General Medicine Ligands Redox Catalysis Metal Electron Transport Electron transfer Crystallography chemistry visual_art visual_art.visual_art_medium Organometallic Compounds |
| Zdroj: | Angewandte Chemie. 120:6484-6487 |
| ISSN: | 1521-3757 0044-8249 |
| DOI: | 10.1002/ange.200800669 |
| Popis: | An investigation of the electronic interplay between ligand radical(s) and a high-valent metal center in the three-member electron-transfer series shown in the picture reveals that, upon oxidation and removal of both ligand radicals, the chromium center becomes reduced from Cr{sup IV} to Cr{sup III} with concomitant formation of an imidyl radical (NR{center_dot}){sup -}. |
| Databáze: | OpenAIRE |
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