79Br NMR spectroscopy as a practical tool for kinetic analysis
| Autor: | Si Jia Chan, Jason B. Harper, Andrew G. Howe, James M. Hook |
|---|---|
| Rok vydání: | 2009 |
| Předmět: |
Deuterium NMR
Magnetic Resonance Spectroscopy Time Factors Pyridines Analytical chemistry General Chemistry Fluorine-19 NMR Nuclear magnetic resonance spectroscopy Bromine Kinetics chemistry.chemical_compound chemistry Heteronuclear molecule Computational chemistry Bromide Heck reaction Benzyl Compounds Pyridine General Materials Science Transverse relaxation-optimized spectroscopy |
| Zdroj: | Magnetic Resonance in Chemistry. 47:342-347 |
| ISSN: | 1097-458X 0749-1581 |
| Popis: | 79Br NMR spectroscopy has been used to monitor a series of reactions in which the bromide ion is produced, including the Menschutkin reaction of pyridine with a range of substituted benzyl bromides and a Heck coupling process. In cases where the process could also be monitored using 1H NMR spectroscopy, the kinetic analyses using heteronuclear magnetic resonance spectroscopy were shown to be completely consistent. Both the utility of the process in following reactions which may be difficult to analyse using other techniques and the practical limitations associated with solvent choice are discussed. Copyright © 2009 John Wiley & Sons, Ltd. |
| Databáze: | OpenAIRE |
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