First structurally authenticated zinc alkylperoxide: a model system for the epoxidation of enones

Autor:	Zbigniew Ochal, Ewa Tratkiewicz, Iwona Justyniak, Emil Bojarski, Janusz Lipkowski, Janusz Lewiński
Rok vydání:	2003
Předmět:	chemistry.chemical_compound chemistry Organic chemistry chemistry.chemical_element Model system Reactivity (chemistry) General Medicine General Chemistry Zinc Peroxide Enone Catalysis
Zdroj:	Angewandte Chemie (International ed. in English). 42(38)
ISSN:	1433-7851
Popis:	How-ever, despite the long history of studies on the reaction oforganozinc compounds with dioxygen, there have been noreportsofthestructurallyauthenticatedzincalkylperoxide;controlling and understanding the reactivity of zinc alkylcomplexes with dioxygen is a demanding task. It should bealso noted that the structural data for main-group metalalkylperoxidesareverylimitedbecauseofthehighreactivityandoftenlowstabilityofthisgroupofcompounds.
Databáze:	OpenAIRE
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