From carbones to carbenes and ylides in the coordination sphere of iridium

Autor:	Leon Maser, Zhuofeng Ke, Yinwu Li, Robert Langer, Lukas Alig
Rok vydání:	2021
Předmět:	chemistry.chemical_classification Coordination sphere Ligand chemistry.chemical_element Pincer movement Catalysis Inorganic Chemistry chemistry.chemical_compound Transition metal chemistry Ylide Polymer chemistry Iridium Phosphine
Zdroj:	Dalton Transactions. 50:954-959
ISSN:	1477-9234 1477-9226
Popis:	The carbodiphosphorane-based iridium pincer complex (2) is demonstrated to rearrange in chlorinated organic solvents under cleavage of a P-C-bond to give a chelating phosphine ylide ligand. A detailed mechanistic investigation reveals that these types of donor groups are prone for P-C-bond cleavage in the coordination sphere of transition metal hydrido complexes. Finally, complex 2 is demonstrated to be an efficient hydrogen-borrowing catalyst.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::35293591cd9ac5cc5867fd2d08409d68 https://doi.org/10.1039/d0dt03942j Zobrazit plný text záznamu