Lithium–nitrogen and lithium–boron–nitrogencage compounds formed using the phenylhydrazido backbone

Autor:	John C. Jeffery, John M. Slattery, Garreth M. Aspinall, Christopher A. Russell, Angela P. Breakspear, May C. Copsey
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Inorganic chemistry chemistry.chemical_element Salt (chemistry) Crystal structure Nitrogen Inorganic Chemistry Dilithium chemistry.chemical_compound Crystallography chemistry Lithium Cage Boron Phenylhydrazine
Zdroj:	Dalton Trans.. :1234-1238
ISSN:	1477-9234 1477-9226
DOI:	10.1039/b510103d
Popis:	Two rare examples of the crystal structures of large molecular clusters formed from the lithium salts of multianions are reported; the first is the dilithium salt of phenylhydrazine, which forms a tetrameric cage with a core of eight Li and eight N centres; the second is a 32-membered cage which forms from the aggregation of two [B(NNPh)3]6- hexaanions, two [NH-NPh]2- dianions and 16 Li+ cations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::34b8504e936d85860e474e44f769dc35 https://doi.org/10.1039/b510103d Zobrazit plný text záznamu