Supramolecular chirogenesis in zinc porphyrins by enantiopure hemicucurbit[n]urils (n = 6, 8)
| Autor: | Jasper Adamson, Tatsiana Burankova, Nele Konrad, Victor V. Borovkov, Lukas Ustrnul, Peeter Burk, Sandra Kaabel, Jevgenija Martõnova, Riina Aav |
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| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Metals and Alloys Supramolecular chemistry chemistry.chemical_element General Chemistry Zinc Crystal structure 010402 general chemistry 01 natural sciences Porphyrin Solution phase Catalysis 3. Good health 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Crystallography Enantiopure drug chemistry Materials Chemistry Ceramics and Composites Molecule Chirality (chemistry) |
| Zdroj: | Chemical Communications |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Chiral cyclohexanohemicucurbit[n]urils (n = 6, 8) (cycHCs) are able to bind guests through multiple "outer surface interactions", which in the case of planar zinc porphyrins leads to induction of chirality. Crystal structures of complexes of complementary sized hosts revealed social self-sorting, while in the solution phase one cycHC can accommodate up to three porphyrin molecules with log Ktotal 9. |
| Databáze: | OpenAIRE |
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