The Versatile Reaction Chemistry of an Alpha-Boryl Diazo Compound
| Autor: | Bo Li, Raimon Puig de la Bellacasa, Yao Liu, Shih-Yuan Liu, Ana Belén Cuenca |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Boron Compounds
Cycloaddition Reaction Esterification Halogenation Chemistry Isostere General Chemistry Biochemistry Combinatorial chemistry Catalysis Cycloaddition Article Ruthenium chemistry.chemical_compound Colloid and Surface Chemistry Coordination Complexes Reactivity (chemistry) Diazo Azo Compounds |
| Zdroj: | J Am Chem Soc |
| Popis: | The first α-boryl diazo compound that is capable of engaging in classic synthetic organic diazo reaction chemistry is described. The diazomethyl-1,2-azaborine 1, which is a BN isostere of phenyldiazomethane, is significantly more stable than phenyldiazomethane; its reaction chemistry ranges from C-H activation, O-H activation, [3+2] cycloaddition, and halogenation, to Ru-catalyzed carbonyl olefination. The demonstrated broad range of reactivity of diazomethyl-1,2-azaborine 1 makes it an exceptionally versatile synthetic building block for the 1,2-azaborine heterocyclic motif. |
| Databáze: | OpenAIRE |
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