Multilocation field trials for risk assessment of a combination fungicide Fluopicolide + Propamocarb in tomato
Autor: | V. R. Shukla, Ram K. Hudait, Tirthankar Banerjee, Kirti Sharma, Debi Sharma, Paresh G Shah, Sanjay Kumar Sahoo, AR Patel, Vandana Tripathy, Balwinder Singh, Hemlatta K. Patel, Kiran M Vaghela, Hemanta Banerjee |
---|---|
Rok vydání: | 2016 |
Předmět: |
India
010501 environmental sciences Management Monitoring Policy and Law Risk Assessment 01 natural sciences Gas Chromatography-Mass Spectrometry Toxicology chemistry.chemical_compound Solanum lycopersicum Limit of Detection 0105 earth and related environmental sciences General Environmental Science Mathematics Residue (complex analysis) Pesticide residue Ecology 010401 analytical chemistry Pesticide Residues General Medicine Pollution Fungicides Industrial 0104 chemical sciences Fungicide chemistry Benzamides Fluopicolide Propamocarb Carbamates Risk assessment Environmental Monitoring Half-Life |
Zdroj: | Environmental Monitoring and Assessment. 188 |
ISSN: | 1573-2959 0167-6369 |
DOI: | 10.1007/s10661-016-5610-y |
Popis: | Dissipation kinetics of two systemic fungicides, namely fluopicolide and propamocarb used as a combination formulation (Infinito 68.75 SC), were studied on tomato at four different locations by the All India Network Project on Pesticide Residues to recommend their pre-harvest interval (PHI) and to propose the maximum residue limits (MRL) for the two fungicides based on chronic hazard exposure assessment. The combination fungicide was sprayed thrice at the recommended dosage of 93.75 g a.i./ha fluopicolide and 937.50 g a.i./ha propamocarb as well as at double the recommended dosage of 187.50 g a.i./ha fluopicolide and 1875.0 g a.i./ha propamocarb on tomato crops and the residues were monitored periodically by GC-MS. The fungicides dissipated to below the limit of quantification (LOQ) within 10 to 15 days, with a half-life of 2-4 days for fluopicolide and 1-2 days for propamocarb. Taking into consideration the MRLs of codex and calculations made using the method of MRL fixation of the Food Safety and Standard Authority of India (FSSAI) as well as the Organization for Economic Co-operation and Development (OECD) calculator, MRL of 5 mg/kg is proposed for fluopicolide and 15 mg/kg for propamocarb, following critical exposure of the commodity considering PHI of 1 day. |
Databáze: | OpenAIRE |
Externí odkaz: |